Consider the following redox reaction :
$MnO_4^{-} + H^{+} + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$
The standard reduction potentials are given as below $(E_{red}^{\circ})$ :
$E_{MnO_4^{-} / Mn^{2+}}^{\circ} = +1.51 \ V$
$E_{CO_2 / H_2C_2O_4}^{\circ} = -0.49 \ V$
If the equilibrium constant of the above reaction is given as $K_{eq} = 10^x$,then the value of $x = $ . . . . . . (nearest integer).
$MnO_4^{-} + H^{+} + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$
The standard reduction potentials are given as below $(E_{red}^{\circ})$ :
$E_{MnO_4^{-} / Mn^{2+}}^{\circ} = +1.51 \ V$
$E_{CO_2 / H_2C_2O_4}^{\circ} = -0.49 \ V$
If the equilibrium constant of the above reaction is given as $K_{eq} = 10^x$,then the value of $x = $ . . . . . . (nearest integer).
- A$339$
- B$350$
- C$390$
- D$340$
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Calculate the equilibrium constant at $298 \ K$ for the following reaction and also calculate the maximum work that can be obtained from this cell:
$Mg(s) \ | \ Mg^{2+}(aq) \ || \ Ag^{+}(aq) \ | \ Ag(s)$
Given: $E_{Mg^{2+} \mid Mg}^{o} = -2.37 \ V$ and $E_{Ag^{+} \mid Ag}^{o} = 0.80 \ V$
$Mg(s) \ | \ Mg^{2+}(aq) \ || \ Ag^{+}(aq) \ | \ Ag(s)$
Given: $E_{Mg^{2+} \mid Mg}^{o} = -2.37 \ V$ and $E_{Ag^{+} \mid Ag}^{o} = 0.80 \ V$
Which of the following statements is not correct $:-$
Medium
View SolutionThe conductivity of $0.01 \ M$ aqueous acetic acid measured with a conductivity cell of cell constant $0.5 \ cm^{-1}$ at $298 \ K$ is $3.12 \times 10^{-4} \ S$. If the limiting molar conductivities of $H^{+}$ and $CH_3COO^{-}$ at the same temperature are $349$ and $41 \ S \ cm^2 \ mol^{-1}$ respectively,the dissociation constant of acetic acid is
Consider the following data.
Electrolyte $\Lambda_m^\circ$ $(S\text{ cm}^2\text{ mol}^{-1})$ $BaCl_2$ $x_1$ $H_2SO_4$ $x_2$ $HCl$ $x_3$
$BaSO_4$ is sparingly soluble in water. If the conductivity of the saturated $BaSO_4$ solution is $x\text{ S cm}^{-1}$,then the solubility product of $BaSO_4$ can be given as (Here $\Lambda_m = \Lambda_m^\circ$)
| Electrolyte | $\Lambda_m^\circ$ $(S\text{ cm}^2\text{ mol}^{-1})$ |
|---|---|
| $BaCl_2$ | $x_1$ |
| $H_2SO_4$ | $x_2$ |
| $HCl$ | $x_3$ |
$BaSO_4$ is sparingly soluble in water. If the conductivity of the saturated $BaSO_4$ solution is $x\text{ S cm}^{-1}$,then the solubility product of $BaSO_4$ can be given as (Here $\Lambda_m = \Lambda_m^\circ$)
DifficultJEE MAIN 2026
View SolutionCalculate the standard cell potentials of galvanic cells in which the following reactions take place:
$(i)$ $2Cr_{(s)} + 3Cd^{2+}_{(aq)} \rightarrow 2Cr^{3+}_{(aq)} + 3Cd_{(s)}$
$(ii)$ $Fe^{2+}_{(aq)} + Ag^{+}_{(aq)} \rightarrow Fe^{3+}_{(aq)} + Ag_{(s)}$
Calculate the $\Delta_r G^\Theta$ and equilibrium constant of the reactions.
$(i)$ $2Cr_{(s)} + 3Cd^{2+}_{(aq)} \rightarrow 2Cr^{3+}_{(aq)} + 3Cd_{(s)}$
$(ii)$ $Fe^{2+}_{(aq)} + Ag^{+}_{(aq)} \rightarrow Fe^{3+}_{(aq)} + Ag_{(s)}$
Calculate the $\Delta_r G^\Theta$ and equilibrium constant of the reactions.
Difficult
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