Identify the correct order of reactivity for the following pairs towards the respective mechanism:
$(A)$ $S_{N}2$: Isobutyl bromide > tert-Butyl bromide
$(B)$ $S_{N}1$: Benzyl bromide > $2-$Phenylethyl bromide
$(C)$ Electrophilic substitution: Chlorobenzene > $1-$Chloro$-4-$nitrobenzene
$(D)$ Nucleophilic substitution: Bromobenzene < $1-$Bromo$-4-$nitrobenzene
Choose the correct answer from the options given below:

  • A
    $A$,$B$ and $D$ only
  • B
    $A$,$B$,$C$ and $D$
  • C
    $A$,$C$ and $D$ only
  • D
    $B$,$C$ and $D$ only

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In the following scheme of reaction,$X, Y$ and $Z$ respectively are:

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| List-$I$ | List-$II$ |
| :--- | :--- |
| $A$. $C_6H_5Cl + CH_3Cl + 2Na \rightarrow C_6H_5CH_3 + 2NaCl$ | $I$. Wurtz-Fitting reaction |
| $B$. $2C_6H_5Cl + 2Na \rightarrow C_6H_5-C_6H_5 + 2NaCl$ | $II$. Fitting reaction |
| $C$. $C_6H_5N_2^+Cl^- \xrightarrow{Cu_2Cl_2} C_6H_5Cl + N_2$ | $III$. Sandmeyer reaction |
| $D$. $C_2H_5Cl + NaI \rightarrow C_2H_5I + NaCl$ | $IV$. Finkelstein reaction |

How many $(\sigma)$ and $(\pi)$ bonds are present in the structure of $DDT$ respectively?

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