Heat is supplied to a diatomic gas at constant pressure. The ratio of $\Delta Q: \Delta U: \Delta W$ is
[Given $\rightarrow \Delta Q=$ heat supplied,$\Delta U=$ change in internal energy,$\Delta W$ $=$ work done]

  • A
    $2: 3: 5$
  • B
    $5: 3: 2$
  • C
    $2: 5: 7$
  • D
    $7: 5: 2$

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What are the limitations of the first law of thermodynamics?

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$A$ small particle of mass $m$ moving inside a heavy, hollow and straight tube along the tube axis undergoes elastic collision at two ends. The tube has no friction and it is closed at one end by a flat surface while the other end is fitted with a heavy movable flat piston as shown in the figure. When the distance of the piston from the closed end is $L = L_0$, the particle speed is $v = v_0$. The piston is moved inward at a very low speed $V$ such that $V \ll \frac{dL}{L} v_0$, where $dL$ is the infinitely small displacement of the piston. Which of the following statement(s) is/are correct?
$(1)$ The rate at which the particle strikes the piston is $v / (2L)$
$(2)$ After each collision with the piston, the particle speed increases by $2V$
$(3)$ The particle's kinetic energy increases by a factor of $4$ when the piston is moved inward from $L_0$ to $L_0 / 2$
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The change in internal energy of a given mass of a gas,when its volume changes from $V$ to $3V$ at constant pressure $P$,is (where $\gamma$ is the ratio of the specific heat capacities of the gas).

$n$ moles of a perfect gas undergo a cyclic process $ABCA$ (see figure) consisting of the following processes:
$A \rightarrow B :$ Isothermal expansion at temperature $T$ so that the volume is doubled from $V_{1}$ to $V_{2}=2V_{1}$ and pressure changes from $P_{1}$ to $P_{2}$.
$B \rightarrow C :$ Isobaric compression at pressure $P_{2}$ to initial volume $V_{1}$.
$C \rightarrow A :$ Isochoric change leading to a change of pressure from $P_{2}$ to $P_{1}$.
Total work done in the complete cycle $ABCA$ is

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