For the reaction,$0.5 C_{(s)} + 0.5 CO_{2(g)} \rightleftharpoons CO_{(g)}$,the equilibrium pressure is $12 \ atm$. If $CO_2$ conversion is $50 \%$,the value of $K_p$,in $atm$,is:

  • A
    $4$
  • B
    $1$
  • C
    $0.5$
  • D
    $2$

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Which one of the following statements is correct for a reversible reaction? $A$ catalyst

Thermal decomposition of gaseous $X_2$ to gaseous $X$ at $298 \ K$ takes place according to the following equation :
$X_{2(g)} \rightleftharpoons 2 X_{(g)}$
The standard reaction Gibbs energy,$\Delta_r G^{\circ}$,of this reaction is positive. At the start of the reaction,there is one mole of $X_2$ and no $X$. As the reaction proceeds,the number of moles of $X$ formed is given by $\beta$. Thus,$\beta_{\text{equilibrium}}$ is the number of moles of $X$ formed at equilibrium. The reaction is carried out at a constant total pressure of $2 \ bar$. Consider the gases to behave ideally. (Given : $R=0.083 \ L \ bar \ K^{-1} \ mol^{-1}$)
$(1)$ The equilibrium constant $K_P$ for this reaction at $298 \ K$,in terms of $\beta_{\text{equilibrium}}$,is
$(A)$ $\frac{8 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(B)$ $\frac{8 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$ $(C)$ $\frac{4 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(D)$ $\frac{4 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$
$(2)$ The $INCORRECT$ statement among the following,for this reaction,is
$(A)$ Decrease in the total pressure will result in formation of more moles of gaseous $X$
$(B)$ At the start of the reaction,dissociation of gaseous $X_2$ takes place spontaneously
$(C)$ $\beta_{\text{equilibrium}}=0.7$
$(D)$ $K_c < 1$

For the reaction,$2SO_{2(g)} + O_{2(g)} \to 2SO_{3(g)}$
$\Delta H = -57.2 \ kJ \ mol^{-1}$ and $K_C = 1.7 \times 10^{16}$
Which of the following statement is $INCORRECT$?

$A$ vessel at $1000 \ K$ contains $CO_2$ with a pressure of $0.5 \ atm$. Some of $CO_2$ is converted into $CO$ on addition of graphite. If total pressure at equilibrium is $0.8 \ atm$,then $K_P$ is : (in $atm$)

Fill in the blanks:
$a$. If a reaction is in equilibrium,then the rate of the forward reaction and the rate of the backward reaction will be ....... .
$b$. If $\Delta G$ is negative,then thermodynamically the reaction takes place in the ...... direction.
$c$. The equilibrium constant gives ........ information for a reaction.

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