For a dilute solution containing $2.5 \ g$ of a non-volatile non-electrolyte solute in $100 \ g$ of water,the elevation in boiling point at $1 \ atm$ pressure is $2^{\circ} C$. Assuming the concentration of solute is much lower than the concentration of solvent,the vapour pressure ($mm$ of $Hg$) of the solution is (take $K_{b}=0.76 \ K \ kg \ mol^{-1}$)

  • A
    $724$
  • B
    $740$
  • C
    $736$
  • D
    $718$

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An aqueous solution of $NaCl$ shows the depression of freezing point of water equal to $0.372 \, K$. The boiling point of $BaCl_2$ solution of same molality will be .........$^oC$. $[K_f(H_2O) = 1.86 \, K \, kg \, mol^{-1}; K_b(H_2O) = 0.52 \, K \, kg \, mol^{-1}]$

On mixing urea,the boiling point of $H_{2}O$ changed to $100.5^{\circ}C$. Calculate the freezing point of the solution,if $K_{f}$ of water is $1.87 \ K \cdot kg \cdot mol^{-1}$ and $K_{b}$ of water is $0.52 \ K \cdot kg \cdot mol^{-1}$. (in $^{\circ}C$)

An aqueous solution of a solute $AB$ has a normal boiling point of $101.08\,^{\circ}C$ and a normal freezing point of $-1.80\,^{\circ}C$. Hence,$AB$:
Given: $AB$ is $100\%$ ionised at the boiling point of the solution,$(K_b / K_f)_{\text{water}} = 0.3$.

Select the correct statement.

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When $1.685 \ g$ of an alkali metal chloride is dissolved in $200 \ g$ water,the boiling point of the solution is measured to be $100.051 \ ^\circ C$. If the ionic solid has a crystal lattice with cation and anion radius $1.70 \ \mathring{A}$ and $1.80 \ \mathring{A}$ respectively,find the edge length of the solid assuming no defect in the crystal. Given: $K_b(H_2O) = 0.51 \ K \ kg \ mol^{-1}$,$N_A = 6 \times 10^{23}$,atomic masses: $[Li = 7, Na = 23, K = 39, Rb = 85.5, Cs = 133, Cl = 35.5]$.

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