Explain the nature of the $C-X$ bond in alkyl halides.

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Halogen atoms are more electronegative than carbon; therefore,the carbon-halogen bond of an alkyl halide is polarized. The carbon atom bears a partial positive charge $(\delta+)$ whereas the halogen atom bears a partial negative charge $(\delta-)$. The bond is represented as $C^{\delta+}-X^{\delta-}$.
As we go down the group in the periodic table,the size of the halogen atom increases. The fluorine atom is the smallest and the iodine atom is the largest. Consequently,the carbon-halogen bond length increases from $C-F$ to $C-I$.
Carbon-Halogen $(C-X)$ Bond Lengths,Bond Enthalpies,and Dipole Moments:
Bond Bond length $/ pm$ $C-X$ Bond enthalpies $/ (kJ \ mol^{-1})$ Dipole moment $/$ Debye
$CH_3F$ $139$ $452$ $1.847$
$CH_3Cl$ $178$ $351$ $1.860$
$CH_3Br$ $193$ $293$ $1.830$
$CH_3I$ $214$ $234$ $1.636$

Order of dipole moment: $CH_3Cl$ > $CH_3F$ > $CH_3Br$ > $CH_3I$
Order of bond enthalpies: $CH_3F$ > $CH_3Cl$ > $CH_3Br$ > $CH_3I$

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