Explain the solubility of a salt in the presence of a common ion.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The solubility of a sparingly soluble salt decreases in the presence of a common ion. This is known as the common ion effect.
According to Le Chatelier's principle,when the concentration of one of the ions (either the cation or the anion) of a sparingly soluble salt is increased by adding a strong electrolyte containing a common ion,the equilibrium shifts to the left to consume the excess ions,resulting in the precipitation of the salt and a decrease in its solubility.
Example $1$: In a saturated solution of $AgCl$,if $NaCl$ is added,the $Cl^{-}$ ion concentration increases. If $AgNO_{3}$ is added,the $Ag^{+}$ ion concentration increases. In both cases,the equilibrium $AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)$ shifts to the left,causing more $AgCl$ to precipitate and decreasing its solubility.
Example $2$: When $HCl$ gas is passed through a saturated solution of $NaCl$,the concentration of $Cl^{-}$ ions increases. This causes the equilibrium $NaCl(s) \rightleftharpoons Na^{+}(aq) + Cl^{-}(aq)$ to shift to the left,leading to the precipitation of solid $NaCl$ and a decrease in its solubility.

Explore More

Similar Questions

The solubility of $AgI$ in $NaI$ is less than that in pure water because ................

Difficult
View Solution

Define the common ion effect and explain it with an example.

Difficult
View Solution

On addition of ammonium chloride to a solution of ammonium hydroxide,what happens to the concentration of $OH^{-}$ ions?

Consider the following equilibrium: $AgCl_{(s)} + 2NH_{3(aq)} \rightleftharpoons [Ag(NH_3)_2]^+_{(aq)} + Cl^-_{(aq)}$. $A$ white precipitate of $AgCl$ appears on adding which of the following?

When $H_2S$ gas is passed through a solution containing $HCl$ during qualitative analysis,cations of the second group are precipitated,but cations of the fourth group are not precipitated because:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo