| Simple distillation | Fractional distillation |
| $(i)$ Used to separate a mixture of two or more miscible liquids for which the difference in boiling point $(b.p.)$ is more than $25^{\circ} C$. | $(i)$ Used to separate two or more miscible liquids for which the difference in boiling point $(b.p.)$ is less than $25^{\circ} C$. |
| $(ii)$ $A$ fractionating column is not used. | $(ii)$ $A$ fractionating column is used to provide more surface area for cooling and condensation. |
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