During the electrolysis of carnallite,$MgCl_2$ is decomposed and not $KCl$. This is because of

In a fuel cell,methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
$CH_3OH_{(l)} + \frac{3}{2} O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)}$
At $298 \ K$,standard Gibbs energies of formation for $CH_3OH_{(l)}$,$H_2O_{(l)}$,and $CO_{2(g)}$ are $-166.2$,$-237.2$,and $-394.4 \ kJ \ mol^{-1}$ respectively. If the standard enthalpy of combustion of methanol is $-726 \ kJ \ mol^{-1}$,the efficiency of the fuel cell will be .......... $\%$.

For a spontaneous reaction,determine the values of $\Delta G^o$,equilibrium constant $K$,and $E^o_{cell}$ respectively.

Consider the following redox reaction :
$MnO_4^{-} + H^{+} + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$
The standard reduction potentials are given as below $(E_{red}^{\circ})$ :
$E_{MnO_4^{-} / Mn^{2+}}^{\circ} = +1.51 \ V$
$E_{CO_2 / H_2C_2O_4}^{\circ} = -0.49 \ V$
If the equilibrium constant of the above reaction is given as $K_{eq} = 10^x$,then the value of $x = $ . . . . . . (nearest integer).

Using the standard electrode potentials given in the Table $8.1$,predict if the reaction between the following is feasible:
$(a)$ $Fe^{3+}_{(aq)}$ and $I^{-}_{(aq)}$
$(b)$ $Ag^{+}_{(aq)}$ and $Cu_{(s)}$
$(c)$ $Fe^{3+}_{(aq)}$ and $Cu_{(s)}$
$(d)$ $Ag_{(s)}$ and $Fe^{3+}_{(aq)}$
$(e)$ $Br_{2(aq)}$ and $Fe^{2+}_{(aq)}$

$A$ and $B$ are two metals. The standard reduction potentials of $A^{+}_{(aq)} / A_{(s)}$ and $B^{+}_{(aq)} / B_{(s)}$ are $-0.5 \ V$ and $+0.5 \ V$ respectively. What is the $\log K_C$ value for the following reaction at $298 \ K$?
$A_{(s)} + B^{+}_{(aq)} \rightleftharpoons A^{+}_{(aq)} + B_{(s)}$
(Given: $\frac{2.303 RT}{F} = 0.06 \ V$)