Discuss the pattern of variation in the oxidation states of $(i)$ $B$ to $Tl$ and $(ii)$ $C$ to $Pb$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(i)$ $B$ to $Tl$: The electronic configuration of group $13$ elements is $ns^2 np^1$. Therefore,the most common oxidation state exhibited by them should be $+3$. However,only boron and aluminium practically show the $+3$ oxidation state. The remaining elements,i.e.,$Ga$,$In$,$Tl$,show both $+1$ and $+3$ oxidation states. On moving down the group,the $+1$ state becomes more stable due to the inert pair effect. The two electrons present in the $s$-shell are strongly attracted by the nucleus and do not participate in bonding. This effect becomes more prominent down the group. Hence,$Ga(+1)$ is unstable,$In(+1)$ is fairly stable,and $Tl(+1)$ is very stable. The stability of the $+3$ oxidation state decreases down the group.
Group $13$ elementOxidation state
$B$$+3$
$Al$$+3$
$Ga, In, Tl$$+1, +3$

$(ii)$ $C$ to $Pb$: The electronic configuration of group $14$ elements is $ns^2 np^2$. Therefore,the most common oxidation state should be $+4$. However,the $+2$ oxidation state becomes more common down the group. $C$ and $Si$ mostly show the $+4$ state. On moving down the group,the higher oxidation state becomes less stable due to the inert pair effect. Thus,although $Ge$,$Sn$,and $Pb$ show both $+2$ and $+4$ states,the stability of the lower oxidation state $(+2)$ increases and that of the higher oxidation state $(+4)$ decreases down the group.
Group $14$ elementOxidation state
$C$$+4$
$Si$$+4$
$Ge, Sn, Pb$$+2, +4$

Stability of $+2$ state increases: $C < Si < Ge < Sn < Pb$
Stability of $+4$ state decreases: $C > Si > Ge > Sn > Pb$

Explore More

Similar Questions

Give the uses of $Al$ and its compounds.

$H_3BO_3$ $\xrightarrow{T_1} X$ $\xrightarrow{T_2} Y$ $\xrightarrow{\text{red hot}} B_2O_3$
If $T_1 < T_2$,then $X$ and $Y$ respectively are:

When orthoboric acid $(H_3BO_3)$ is heated,the residue left is:

Below are two statements,one labeled as Assertion $(A)$ and the other as Reason $(R):$
Assertion $(A)$: Among group $13$ elements,boron's melting point is unusually high $(2453 \ K)$.
Reason $(R):$ Solid boron has a strong crystalline lattice.
In the context of the above statements,choose the correct answer from the following options:

Give the increasing order of group $13$ elements for atomic radius.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo