| Molecule | $P-X$ (axial) bond length / $P-X$ (equatorial) bond length |
| $PF_5$ | $a / b$ |
| $PF_4CH_3$ | $c / d$ |
| $PF_3(CH_3)_2$ | $e / f$ |
| $PCl_5$ | $g / h$ |
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