Consider the following electrochemical cell,$Zn_{(s)} + 2Ag^{+}(0.04\, M) \longrightarrow Zn^{2+}(0.28\, M) + 2Ag_{(s)}$. If $E_{\text{cell}}^{\circ} = 2.57\, V$,then the emf of the cell at $298\, K$ is $......\, V$. (in $.5$)

  • A
    $2$
  • B
    $1$
  • C
    $0$
  • D
    $-0$

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Consider the following cell reaction:
$2 Fe^{3+}_{(aq)} + 2 I^{-}_{(aq)} \rightleftharpoons 2 Fe^{2+}_{(aq)} + I_{2(s)}$
At $298 \ K$,the cell emf is $0.237 \ V$. The equilibrium constant for the reaction is $10^x$. The value of $x$ is:
$(F = 96500 \ C \ mol^{-1}; R = 8.3 \ J \ K^{-1} \ mol^{-1})$

Consider the cell:
$Pt_{(s)} | H_{2(g)}(1 \ atm) | H^{+}_{(aq)}, [H^{+}]=1 \ M || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
Given: $E^0_{Fe^{3+}/Fe^{2+}} = 0.771 \ V$ and $E^0_{H^{+}/\frac{1}{2}H_2} = 0 \ V$ at $T = 298 \ K$.
If the potential of the cell is $0.712 \ V$,the ratio of concentration of $Fe^{2+}$ to $Fe^{3+}$ is $........$. (Nearest integer)

For the cell reaction $Zn(s) + Cu^{2+}(aq) (1.0 \, M) \to Cu(s) + Zn^{2+}(aq) (0.1 \, M)$,the measured $e.m.f.$ at $25 \, ^oC$ is $1.3 \, V$. Calculate the $E^o$ value for the cell reaction. (in $, V$)

What will be the reduction potential of $Cu$ in an aqueous solution with $pH = 12$? Given that the $K_{sp}$ of $Cu(OH)_2$ is $1 \times 10^{-19}$ and $E^{\circ}_{Cu^{+2}/Cu} = 0.34 \ V$.

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Which of the following is correct as a Nernst equation for the given electrochemical cell ?
$Mg_{(s)}|Mg_{(aq)}^{2+}(0.1 \ M)||Cl_{(aq)}^{-}(0.1 \ M)|Cl_{2_{(g)}}(1 \ bar)|Pt_{(s)}$

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