At $298 \ K$,the equilibrium constant of the process $1.5 O_{2(g)} \rightleftharpoons O_{3(g)}$ is $3 \times 10^{-29}$. The standard free energy change (in $kJ \ mol^{-1}$) of the process is approximately ($R = 8.314 \ J \ mol^{-1} \ K^{-1}$; $\log 3 = 0.47$)

  • A
    $724$
  • B
    $612$
  • C
    $247$
  • D
    $163$

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Describe the relationship between Gibbs energy change and chemical equilibrium.

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Consider the reaction $A \rightleftharpoons B$ at $1000 \ K$. At time $t^{\prime}$,the temperature of the system was increased to $2000 \ K$ and the system was allowed to reach equilibrium. Throughout this experiment,the partial pressure of $A$ was maintained at $1 \ bar$. Given below is the plot of the partial pressure of $B$ with time. What is the ratio of the standard Gibbs energy of the reaction at $1000 \ K$ to that at $2000 \ K$?

For a homogeneous gaseous reaction,the equilibrium constant $K_p$ is $10^{-8}$. The standard Gibbs free energy change for the reaction is ........... $kcal$. $(R = 2.0 \, cal \, K^{-1} \, mol^{-1}, T = 298 \, K)$

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