Arrange the following compounds in the increasing order of their boiling points:
$CH_3CH_2CH_2CHO$,$CH_3CH_2CH_2CH_2OH$,$C_2H_5OC_2H_5$,$CH_3CH_2CH_2CH_3$

  • A
    $CH_3CH_2CH_2CH_3 < C_2H_5OC_2H_5 < CH_3CH_2CH_2CHO < CH_3CH_2CH_2CH_2OH$
  • B
    $CH_3CH_2CH_2CH_2OH < CH_3CH_2CH_2CHO < C_2H_5OC_2H_5 < CH_3CH_2CH_2CH_3$
  • C
    $CH_3CH_2CH_2CH_3 < CH_3CH_2CH_2CHO < C_2H_5OC_2H_5 < CH_3CH_2CH_2CH_2OH$
  • D
    $C_2H_5OC_2H_5 < CH_3CH_2CH_2CH_3 < CH_3CH_2CH_2CHO < CH_3CH_2CH_2CH_2OH$

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Column $(I)$ contains products and Column $(II)$ contains the processes to prepare them. Match the processes in Column $(II)$ with the products in Column $(I)$.
Column - $(I)$ Product Column - $(II)$ Preparation Process
$(A)$ Butan$-1-$ol $(i)$ Hydration of propene in the presence of dilute sulfuric acid
$(B)$ Propan$-2-$ol $(ii)$ Reaction of propanone with methylmagnesium bromide followed by hydrolysis
$(C)$ $2-$Methylpropan$-2-$ol $(iii)$ Hydroboration of propene followed by reaction with $(NaOH + H_2O_2)$
$(D)$ Propan$-1-$ol $(iv)$ Catalytic reduction of butanal

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Scheme $1$ and $2$ describe the conversion of $P$ to $Q$ and $R$ to $S$,respectively. Scheme $3$ describes the synthesis of $T$ from $Q$ and $S$. The total number of $Br$ atoms in a molecule of $T$ is. . . . . . . .

What is the increasing order of reactivity of the following alkyl halides in the Williamson synthesis?
$I. \, CH_2 = CHCH_2Cl$
$II. \, CH_3CH_2CH_2Br$
$III. \, (CH_3)_3CCH_2Br$
$IV. \, CH_3CH_2CH_2Cl$

From the following compounds,determine the number of compounds that give $(i)$ a red colouration with ceric ammonium nitrate and $(ii)$ a positive iodoform test: $...........$.

Match the following column:
Column-$I$ (Reaction) Column-$II$ (Electrophile)
$A$. $C_6H_6 + CH_3Cl \xrightarrow{AlCl_3} C_6H_5CH_3$ $P$. $CO_2$
$B$. $C_6H_5OH + CO_2 \xrightarrow[H^+]{NaOH} \text{Salicylic acid}$ $Q$. $:CCl_2$
$C$. $C_6H_5OH + CHCl_3 \xrightarrow{KOH} \text{Salicylaldehyde}$ $R$. $\stackrel{+}{C}H_3$
$D$. $C_6H_6 + SO_3 \xrightarrow{H_2SO_4} C_6H_5SO_3H$ $S$. $\stackrel{+}{S}O_3H$
$T$. $SO_3$

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