Among the following,which one is not formed in the Hoffmann bromamide degradation reaction?

Aniline reacts with mixed acid (conc. $HNO_3$ and conc. $H_2SO_4$) at $288 \ K$ to give $P$ $(51 \%)$,$Q$ $(47 \%)$ and $R$ $(2 \%)$. The major product$(s)$ of the following reaction sequence is (are):
$R$ $\xrightarrow[2) Br_2, CH_3CO_2H]{1) Ac_2O, \text{pyridine}}$ $\xrightarrow{3) H_3O^+}$ $\xrightarrow{4) NaNO_2, HCl / 273-278 \ K}$ $\xrightarrow{5) EtOH, \Delta}$ $\xrightarrow{6) Sn/HCl}$ $\xrightarrow{7) Br_2/H_2O \text{ (excess)}} \text{Major Product}$

In the given reaction sequence,$Z$ is

Which of the following statements is incorrect in case of Hofmann bromamide degradation?

When $R-CO-NH_2$ is treated with $Br_2$ and $KOH$,it gives $R-NH_2$ as the major product. Which intermediate is involved in this reaction?

Nitration of which among the following compounds yields cyclonite?