$A$ gas is compressed isothermally to half its initial volume. The same gas is compressed separately through an adiabatic process until its volume is again reduced to half. Then

The figure below shows two paths that may be taken by a gas to go from a state $A$ to a state $C.$ In process $AB,$ $400 \, J$ of heat is added to the system and in process $BC,$ $100 \, J$ of heat is added to the system. The heat absorbed by the system in the process $AC$ will be ...... $J$

$A$ real gas within a closed chamber at $27^{\circ} C$ undergoes the cyclic process as shown in the figure. The gas obeys the $PV^3 = RT$ equation for the path $A$ to $B$. The net work done in the complete cycle is (assuming $R = 8 \, J/mol \cdot K$): (in $ \, J$)

In Column-$I$ devices and in Column-$II$ efficiency are given. Match them appropriately:

Column-$I$	Column-$II$
$(a)$ Heat engine	$(i)$ $\eta = \frac{Q_2}{Q_1 - Q_2}$
$(b)$ Heat pump	$(ii)$ $\eta = \frac{Q_1 - Q_2}{Q_1}$
	$(iii)$ $\eta = \frac{T_1 - T_2}{T_1}$

In the figure,a container is shown to have a movable (frictionless) piston on top. The container and the piston are made of perfectly insulating material,allowing no heat transfer between the outside and inside. The container is divided into two compartments by a rigid partition made of a thermally conducting material that allows slow heat transfer. The lower compartment is filled with $2$ moles of an ideal monatomic gas at $700 \ K$,and the upper compartment is filled with $2$ moles of an ideal diatomic gas at $400 \ K$. The heat capacities per mole are: for monatomic gas,$C_v = \frac{3}{2} R, C_p = \frac{5}{2} R$; for diatomic gas,$C_v = \frac{5}{2} R, C_p = \frac{7}{2} R$.
$1.$ Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved,the final temperature of the gases will be:
$(A) 550 \ K$ $(B) 525 \ K$ $(C) 513 \ K$ $(D) 490 \ K$
$2.$ Now consider the partition to be free to move without friction so that the pressure of gases in both compartments is the same. Then the total work done by the gases until they achieve equilibrium will be:
$(A) 250 \ R$ $(B) 200 \ R$ $(C) 100 \ R$ $(D) -100 \ R$
Give the answer for questions $1$ and $2$.

Choose the incorrect statement from the following:
$S1$: The efficiency of a heat engine can be $1$,but the coefficient of performance of a refrigerator can never be infinity.
$S2$: The first law of thermodynamics is basically the principle of conservation of energy.
$S3$: The second law of thermodynamics does not allow several phenomena consistent with the first law.
$S4$: $A$ process,whose sole result is the transfer of heat from a colder to a hotter object,is impossible.