$A$ blue colouration is not obtained when:

  • A
    Ammonium hydroxide dissolves in copper sulphate
  • B
    Copper sulphate solution reacts with $K_4[Fe(CN)_6]$
  • C
    Ferric chloride reacts with sodium ferrocyanide
  • D
    Anhydrous $CuSO_4$ is dissolved in water

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Match List-$I$ with List-$II$ and select the correct option:
List-$I$List-$II$
$(A). [Ag(CN)_2]^-$$1. \text{Square planar, } 1.73 \, B.M.$
$(B). [Cu(CN)_4]^{3-}$$2. \text{Linear, } 0 \, B.M.$
$(C). [Cu(CN)_6]^{4-}$$3. \text{Octahedral, } 0 \, B.M.$
$(D). [Cu(NH_3)_4]^{2+}$$4. \text{Tetrahedral, } 0 \, B.M.$
$(E). [Fe(CN)_6]^{4-}$$5. \text{Octahedral, } 1.73 \, B.M.$

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The colour of $CuCr_2O_7$ solution in water is green because

Among the statements $(a)-(d)$,the incorrect ones are:
$(a)$ Octahedral $Co(III)$ complexes with strong field ligands have very high magnetic moments.
$(b)$ When $\Delta_{0} < P$,the $d-$electron configuration of $Co(III)$ in an octahedral complex is $t_{2g}^{4} e_{g}^{2}$.
$(c)$ Wavelength of light absorbed by $[Co(en)_{3}]^{3+}$ is lower than that of $[CoF_{6}]^{3-}$.
$(d)$ If the $\Delta_{0}$ for an octahedral complex of $Co(III)$ is $18,000 \ cm^{-1}$,the $\Delta_{t}$ for its tetrahedral complex with the same ligand will be $16,000 \ cm^{-1}$.

Given below are two statements:
Statement-$I$: Hybridisation,shape,and spin-only magnetic moment of $K_{3}[Co(CO_{3})_{3}]$ are $sp^{3}d^{2}$,octahedral,and $4.9 \ BM$ respectively.
Statement-$II$: Geometry,hybridisation,and spin-only magnetic moment values $(BM)$ of the ions $[Ni(CN)_{4}]^{2-}$,$[MnBr_{4}]^{2-}$,and $[CoF_{6}]^{3-}$ respectively are square planar,tetrahedral,octahedral; $dsp^{2}$,$sp^{3}$,$sp^{3}d^{2}$ and $0, 5.9, 4.9$.

Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists.
$\{ en = H_2NCH_2CH_2NH_2 \}$; atomic numbers: $\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$
List-$I$ List-$II$
$P.$ $[Cr(NH_3)_4Cl_2]Cl$ $1.$ Paramagnetic and exhibits ionisation isomerism
$Q.$ $[Ti(H_2O)_5Cl](NO_3)_2$ $2.$ Diamagnetic and exhibits cis-trans isomerism
$R.$ $[Pt(en)(NH_3)_2Cl_2]NO_3$ $3.$ Paramagnetic and exhibits cis-trans isomerism
$S.$ $[Co(NH_3)_4(NO_3)_2]NO_3$ $4.$ Diamagnetic and exhibits ionisation isomerism
Codes: $P, Q, R, S$

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