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In aluminium extraction by the Bayer process,alumina is extracted from bauxite by sodium hydroxide at high temperature and pressure: $Al_2O_{3(s)} + 2 OH^-_{(aq)} + 3 H_2O_{(l)} \rightarrow 2 [Al(OH)_4]^-_{(aq)}$. Solid impurities such as $Fe_2O_3$ and $SiO_2$ are removed and then $[Al(OH)_4]^-$ is reprecipitated: $2 [Al(OH)_4]^-_{(aq)} \rightarrow Al_2O_3 \cdot 3 H_2O_{(s)} + 2 OH^-_{(aq)}$. In the industrial world:

Consider the following:
Statement-$I$ : In the extraction of $Al$ by Hall-Heroult process,pure $Al_2O_3$ mixed with $Na_3AlF_6$ lowers its melting point and increases conductivity.
Statement-$II$ : Zirconium metal is purified by zone refining method.

Match List $I$ with List $II$.
List $I$ List $II$
$A$. Reverberatory furnace $I$. Pig Iron
$B$. Electrolytic cell $II$. Aluminum
$C$. Blast furnace $III$. Silicon
$D$. Zone Refining furnace $IV$. Copper

Given below are two statements:
Statement $I$: During electrolytic refining,the pure metal is made to act as anode and its impure metallic form is used as cathode.
Statement $II$: During the Hall-Heroult electrolysis process,purified $Al_2O_3$ is mixed with $Na_3AlF_6$ to lower the melting point of the mixture.
In the light of the above statements,choose the most appropriate answer from the options given below:

List-$I$ contains different compounds formed during the extraction of metal $(M)$ in List-$II$. Match the compounds in List-$I$ with the corresponding metal and process in List-$II$.
List-$I$ List-$II$
$(P). [M(CN)_2]^-$ $(1). Ni$ (during refining of metal)
$(Q). [M(CO)_4]$ $(2). Ti$ (during refining of metal)
$(R). MI_4$ $(3). Pb$ (during roasting of ore)
$(S). MO$ $(4). Ag$ (during leaching of ore)

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