A coordination compound with the formula FeCl | vedclass

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(D) $1$. The formula is $FeCl_3 \cdot 4NH_3$. Since it gives a white precipitate with $AgNO_3$,at least one $Cl^-$ ion must be outside the coordinatio

Vedclass · Accepted Answer

Tetraamminedichloridoiron $(III)$ chloride

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(D) $1$. The formula is $FeCl_3 \cdot 4NH_3$. Since it gives a white precipitate with $AgNO_3$,at least one $Cl^-$ ion must be outside the coordination sphere.$2$. The coordination number is $6$. With $4$ $NH_3$ ligands,we need $2$ more ligands to satisfy the coordination number of $6$. These must be $Cl^-$ ions.$3$. The complex can be written as $[Fe(NH_3)_4Cl_2]Cl$.$4$. The $IUPAC$ name for $[Fe(NH_3)_4Cl_2]Cl$ is tetraamminedichloridoiron $(III)$ chloride.

$A$ coordination compound with the formula $FeCl_3 \cdot 4NH_3$ has a coordination number of $6$ for the central metal ion. It does not lose $NH_3$ gas upon heating but gives a white precipitate with an aqueous solution of $AgNO_3$. What is the $IUPAC$ name of this complex?

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