For the reaction $A + B \rightleftharpoons C + D$ at $250^\circ C$ in a $1 \ L$ vessel,the initial concentration of $A$ is $3$ and $B$ is $n$. If the equilibrium concentration of $C$ is equal to the equilibrium concentration of $B$,what is the equilibrium concentration of $D$?

For the reaction $2SO_3 \rightleftharpoons 2SO_2 + O_2$,if $K_c = 100$ and the degree of dissociation $\alpha = 1$,determine the concentration of $O_2$ when the concentration of $SO_3$ is equal to the concentration of $SO_2$.

The equilibrium constants for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$ are $K_{1}$ and $K_{2}$,respectively. If the initial concentrations and the degree of dissociation of $X$ and $Z$ are the same,the ratio $K_{1} / K_{2}$ is

The reaction $2 NO_{2(g)} \rightleftharpoons N_2O_{4(g)}$ is at equilibrium in a closed $15 \ L$ vessel at $300 \ K$. The total weight of the mixture of $NO_2$ and $N_2O_4$ in the vessel is $64.4 \ g$. The equilibrium constant for the reaction is $K_p = 6.67$. Assuming ideal gas behavior,the total pressure in the vessel (in $atm$) is: [Given: Gas constant $R = 0.082 \ atm \ L \ K^{-1} \ mol^{-1}$]

$2NOBr_{(g)} \rightleftharpoons 2NO_{(g)} + Br_{2_{(g)}}$. If $NOBr$ is $40\%$ dissociated at a certain temperature and a total pressure of $0.30 \text{ atm}$,the $K_p$ for the reaction $2NO_{(g)} + Br_{2_{(g)}} \rightleftharpoons 2NOBr_{(g)}$ is:

Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?