At high temperature,$2 \, \text{mol}$ of $NH_3$ is placed in a $500 \, \text{mL}$ vessel. For the decomposition reaction $2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}$,if $1 \, \text{mol}$ of $NH_3$ remains at equilibrium,then $K_c$ is equal to:

  • A
    $0.42$
  • B
    $6.75$
  • C
    $1.7$
  • D
    $1.5$

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Calculate:
$(a)$ $\Delta G^{\circ}$ and
$(b)$ the equilibrium constant for the formation of $NO_2$ from $NO$ and $O_2$ at $298 \, K$
$NO_{(g)} + 1/2 O_{2(g)} \longleftrightarrow NO_{2(g)}$
Given:
$\Delta G^{\circ}_f(NO_2) = 52.0 \, kJ/mol$
$\Delta G^{\circ}_f(NO) = 87.0 \, kJ/mol$
$\Delta G^{\circ}_f(O_2) = 0 \, kJ/mol$

For the reaction $XCO_{3(s)} \rightleftharpoons XO_{(s)} + CO_{2(g)},$ $K_p = 1.642 \text{ atm}$ at $727^{\circ}C.$ If $4 \text{ moles}$ of $XCO_{3(s)}$ were placed into a $50 \text{ L}$ container and heated to $727^{\circ}C,$ what mole percent of the $XCO_3$ remains unreacted at equilibrium?

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One mole of $N_2O_4(g)$ is taken in a closed container at $1 \ atm$ and $300 \ K$. When it is heated to $600 \ K$,$20 \%$ of $N_2O_4(g)$ dissociates into $NO_2(g)$. The resulting pressure is .......... $atm$.

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The equilibrium constant $K_c$ for the following equilibrium:
$2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$
at $563 \ K$ is $100$. At equilibrium,the number of moles of $SO_3$ in the $10 \ L$ flask is twice the number of moles of $SO_2$. Calculate the number of moles of oxygen.

In a closed vessel at $448^{\circ} C$,$0.5 \ mol$ of $H_2$ and $0.5 \ mol$ of $I_2$ react to form hydrogen iodide.
Reaction: $H_{2(g)} + I_{2(g)} \rightleftharpoons 2HI_{(g)}$,$K_c = 50$.
$(i)$ Calculate the moles of $I_2$ that remain unreacted at equilibrium.
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