Which of the following statements is incorrect?

  • A
    The half-life of a first-order reaction is independent of its initial concentration.
  • B
    For a first-order reaction,the rate of reaction remains constant.
  • C
    The unit of $K$ for a second-order reaction is $mol^{-1} \text{ } L \text{ } s^{-1}$.
  • D
    None of these.

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Similar Questions

$A$ reaction between two different reactants cannot be a .....

Write the differential rate expression for the following reaction and determine its order of reaction:
$5 Br^{-} + BrO_3^{-} + 6 H^{+} \rightarrow 3 Br_2 + 3 H_2 O$

The following data is given for the reaction between $A$ and $B$:
$S.NO.$$[A] \ mol \ L^{-1}$$[B] \ mol \ L^{-1}$$Rate \ mol \ L^{-1} \ sec^{-1}$
$I$$1 \times 10^{-2}$$2 \times 10^{-2}$$2 \times 10^{-4}$
$II$$2 \times 10^{-2}$$2 \times 10^{-2}$$4 \times 10^{-4}$
$III$$2 \times 10^{-2}$$4 \times 10^{-2}$$8 \times 10^{-4}$

Which of the following are correct statements?
$(a)$ Rate constant of the reaction is $1 \ mol^{-1} \ L \ sec^{-1}$.
$(b)$ Rate law of the reaction is $k[A][B]$.
$(c)$ Rate of reaction increases four times on doubling the concentration of both the reactants.

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The reaction $CH_{3}COF + H_{2}O \rightleftharpoons CH_{3}COOH + HF$ is studied under two conditions:
Condition $I$: $[H_{2}O]_{0} = 1.00 \ M$,$[CH_{3}COF]_{0} = 0.01 \ M$
Condition $II$: $[H_{2}O]_{0} = 0.02 \ M$,$[CH_{3}COF]_{0} = 0.80 \ M$
Time $(t)$ min (Condition $I$) / $[CH_{3}COF]$ $M$ Time $(t)$ min (Condition $II$) / $[H_{2}O]$ $M$
$0$ / $0.01000$ $0$ / $0.0200$
$10$ / $0.00867$ $10$ / $0.0176$
$20$ / $0.00735$ $20$ / $0.0156$
$40$ / $0.00540$ $40$ / $0.0122$

Determine the overall order of the reaction and calculate the rate constant.

The data for the reaction $A + B \to C$ is given below. The rate law corresponding to the above data is:
$Exp.$ $[A]_0$ $[B]_0$ Initial rate
$(1)$ $0.012$ $0.035$ $0.10$
$(2)$ $0.024$ $0.070$ $0.80$
$(3)$ $0.024$ $0.035$ $0.10$
$(4)$ $0.012$ $0.070$ $0.80$

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