When the temperature changes from $293 \ K$ to $313 \ K$,the rate of a certain reaction becomes four times. Find the activation energy of the reaction in $kJ \ mol^{-1}$. $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$

  • A
    $45.68$
  • B
    $52.86$
  • C
    $53.69$
  • D
    $58.93$

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$A$ reaction takes place in three steps with individual rate constant and activation energy,
Step Rate constant and Activation energy
$Step \ 1$ $k_1, E_{a_1} = 180 \ kJ \ mol^{-1}$
$Step \ 2$ $k_2, E_{a_2} = 80 \ kJ \ mol^{-1}$
$Step \ 3$ $k_3, E_{a_3} = 50 \ kJ \ mol^{-1}$

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The rate constant for the first order decomposition of a certain reaction is described by the equation $\ln k (s^{-1}) = 14.34 - \frac{1.25 \times 10^{4} \ K}{T}$. The energy of activation for this reaction is

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