For a reversible reaction $A \rightleftharpoons B$,the $\Delta H_{\text{forward}} = 20 \ kJ \ mol^{-1}$. The activation energy of the uncatalysed forward reaction is $300 \ kJ \ mol^{-1}$. When the reaction is catalysed keeping the reactant concentration same,the rate of the catalysed forward reaction at $27^{\circ}C$ is found to be same as that of the uncatalysed reaction at $327^{\circ}C$. The activation energy of the catalysed backward reaction is $.... \ kJ \ mol^{-1}$.

  • A
    $130$
  • B
    $120$
  • C
    $110$
  • D
    $100$

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For the gaseous reactions,calculate the approximate value of temperature at which $k_1 = k_2$. $[ln\, 10 = 2.3]$.
$A \to B$ $k_1 = 10^{15} e^{-25000 / 8.314\, T}$
$C \to D$ $k_2 = 10^{14} e^{-15000 / 8.314\, T}$

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