Which of the following compounds changes the color of an aqueous $FeCl_3$ solution?

Sometimes yellow turbidity appears on passing $H_2S$ gas even in the absence of the second group radicals. This happens because

On treating a solid salt $A$ with dil. $H_2SO_4$ and warming,reddish-brown fumes of gas $B$ are evolved. Addition of $C$ to the salt solution of $A$ followed by freshly prepared starch solution and acidification with acetic acid produces a blue colour. $C$ may contain:

$A$ (Orange color compound) $\xrightarrow{(B) + \text{conc. } H_2SO_4}$ $C$ (Red gas) $\xrightarrow{NaOH + AgNO_3}$ $D$ (Red ppt.) $\xrightarrow{\text{NH}_3 \text{ solution}}$ Yellow solution.
$B$ $\xrightarrow[\Delta]{NaOH}$ $F \uparrow$ (Gives white fumes with $HCl$).
Identify $B$ and $F$ respectively :-

Consider the following reaction scheme: $D(\text{White ppt}) \xleftarrow{Na_2CO_3} A \xrightarrow[\text{in acetic acid}]{K_2CrO_4} B(\text{Yellow ppt})$ and $A \xrightarrow{dil.\ H_2SO_4} C(\text{White ppt})$. If $A$ is a metallic salt,then the white precipitate $D$ must be:

The only cations present in a slightly acidic solution are $Fe^{3+}$,$Zn^{2+}$,and $Cu^{2+}$. The reagent that when added in excess to this solution would identify and separate $Fe^{3+}$ in one step is