Given $C + O_2 \rightarrow CO_2 + 94.2 \ kcal$,$\Delta H = -94.2 \ kcal$; $H_2 + 1/2 O_2 \rightarrow H_2O + 68.3 \ kcal$,$\Delta H = -68.3 \ kcal$ and $CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O + 210.8 \ kcal$,$\Delta H = -210.8 \ kcal$. Calculate the heat of formation of methane $(CH_4)$ in $kcal$.

For the reaction $2H_{2(g)} + O_{2(g)} \to 2H_2O_{(l)}$,the enthalpy change is $\Delta H = -571 \ kJ$. If the $H-H$ bond energy is $435 \ kJ \ mol^{-1}$ and the $O=O$ bond energy is $498 \ kJ \ mol^{-1}$,calculate the average bond energy of the $O-H$ bond in $kJ \ mol^{-1}$.

Calculate the standard enthalpy of formation of $CH_{3}OH_{(l)}$ from the following data:
$CH_{3}OH_{(l)} + \frac{3}{2} O_{2_{(g)}} \rightarrow CO_{2_{(g)}} + 2 H_{2}O_{(l)}$; $\Delta_{r} H^{\ominus} = -726 \ kJ \ mol^{-1}$
$C_{(graphite)} + O_{2_{(g)}} \rightarrow CO_{2_{(g)}}$; $\Delta_{c} H^{\ominus} = -393 \ kJ \ mol^{-1}$
$H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \rightarrow H_{2}O_{(l)}$; $\Delta_{f} H^{\ominus} = -286 \ kJ \ mol^{-1}$

What will be the standard heat of reaction for the reaction $C_2H_{6(g)} + 7/2 O_{2(g)} \to 2CO_{2(g)} + 3H_2O_{(l)}$ if the standard heat of combustion of $C_{(s)}$ and $H_{2(g)}$ are $-393.5 \ kJ/mol$ and $-285 \ kJ/mol$ respectively,and the standard heat of formation of $C_2H_{6(g)}$ is $-88.2 \ kJ/mol$?

$S + \frac{3}{2} O_2 \to SO_3 + 2x \ kcal$
$SO_2 + \frac{1}{2} O_2 \to SO_3 + y \ kcal$
Find out the heat of formation of $SO_2$.

Bond dissociation enthalpy of $H_2, Cl_2$ and $HCl$ are $434, 242$ and $431 \ kJ \ mol^{-1}$ respectively. Enthalpy of formation of $HCl$ is ............... $kJ \ mol^{-1}$