$Isopropyl$ amine with an excess of acetyl chloride will give:

  • A
    $((CH_{3}CO)_{2}N-CH(CH_{3})_{2})$
  • B
    $CH_{3}CONHCH(CH_{3})_{2}$
  • C
    $((CH_{3})_{2}CHN(COCH_{3})_{2})$
  • D
    None of these

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Arrange the following compounds in the correct order of their basic strength:

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In amines,the hybridisation state of $N$ is

Which of the following does not react with $HNO_2$?

Given below are two statements:
Statement $I$: Aniline is less basic than acetamide.
Statement $II$: In aniline,the lone pair of electrons on nitrogen atom is delocalised over benzene ring due to resonance and hence less available to a proton.
Choose the most appropriate option:

Aniline reacts with mixed acid (conc. $HNO_3$ and conc. $H_2SO_4$) at $288 \ K$ to give $P$ $(51 \%)$,$Q$ $(47 \%)$ and $R$ $(2 \%)$. The major product$(s)$ of the following reaction sequence is (are):
$R$ $\xrightarrow[2) Br_2, CH_3CO_2H]{1) Ac_2O, \text{pyridine}}$ $\xrightarrow{3) H_3O^+}$ $\xrightarrow{4) NaNO_2, HCl / 273-278 \ K}$ $\xrightarrow{5) EtOH, \Delta}$ $\xrightarrow{6) Sn/HCl}$ $\xrightarrow{7) Br_2/H_2O \text{ (excess)}} \text{Major Product}$

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