(N/A) Tooth decay starts when the $pH$ of the mouth falls below $5.5$. This occurs when bacteria present in the mouth produce acids by degrading sugar and food particles remaining in the mouth after eating. Using toothpaste,which is generally basic,helps neutralize the excess acid and prevents tooth decay.
$(b)$ If the $pH$ of a salt solution is greater than $7$,the nature of the salt is basic.
$(i)$ For Potassium sulphate $(K_2SO_4)$: Base is $KOH$ (Potassium hydroxide) and Acid is $H_2SO_4$ (Sulphuric acid).
$(ii)$ For Ammonium chloride $(NH_4Cl)$: Base is $NH_4OH$ (Ammonium hydroxide) and Acid is $HCl$ (Hydrochloric acid).