The reaction of excess ethyl chloride with am | vedclass

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Question

(C) The reaction of an alkyl halide with ammonia is known as ammonolysis. When excess ethyl chloride $(C_2H_5Cl)$ is reacted with ammonia $(NH_3)$,the

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Tetraethylammonium chloride

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(C) The reaction of an alkyl halide with ammonia is known as ammonolysis. When excess ethyl chloride $(C_2H_5Cl)$ is reacted with ammonia $(NH_3)$,the reaction proceeds through successive alkylation steps until all hydrogen atoms on the nitrogen are replaced by ethyl groups. $NH_3 + C_2H_5Cl \rightarrow C_2H_5NH_2 + HCl$ $C_2H_5NH_2 + C_2H_5Cl \rightarrow (C_2H_5)_2NH + HCl$ $(C_2H_5)_2NH + C_2H_5Cl \rightarrow (C_2H_5)_3N + HCl$ $(C_2H_5)_3N + C_2H_5Cl \rightarrow (C_2H_5)_4N^+Cl^-$ Since ethyl chloride is in excess,the final product is the quaternary ammonium salt,tetraethylammonium chloride.

The reaction of excess ethyl chloride with ammonia yields .................. .

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