If the addition of AgNO_3 to a solution of Co | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(B) According to Werner's coordination theory,the chloride ions that are ionizable are those present outside the coordination sphere (primary valency)

Vedclass · Accepted Answer

One chlorine atom satisfies both primary and secondary valency.

Vedclass · Answer

(B) According to Werner's coordination theory,the chloride ions that are ionizable are those present outside the coordination sphere (primary valency). Since the addition of $AgNO_3$ yields $AgCl$ precipitates corresponding to two chloride ions,it implies that two $Cl^-$ ions are outside the coordination sphere. The formula of the complex is $[Co(NH_3)_5Cl]Cl_2$. In this complex,the $Cl^-$ ion inside the square bracket satisfies both primary and secondary valency,while the two $Cl^-$ ions outside the bracket satisfy only primary valency. Therefore,one chlorine atom satisfies both primary and secondary valency.

If the addition of $AgNO_3$ to a solution of $Co(NH_3)_5Cl_3$ results in the precipitation of $AgCl$ corresponding to two ionizable chloride ions,it means that ..............

Similar Questions

The oxidation state and covalency of $Al$ in $[AlCl(H_2O)_5]^{2+}$ are respectively

$NH_2-NH_2$ acts as a .......

What is the number of ions produced by $[Pt(NH_3)_4Cl_2]Cl_2$ in an aqueous solution?

Which of the following compounds is a zero-valent metal complex?

Identify the heteroleptic complex from the following.

Vedclass Test Series

Exam Paper Generator

Online Exam Module