For the reversible reaction $2NO_2 \leftrightarrow[K_2]{K_1} N_2O_4$,the rate of disappearance of $NO_2$ is given by:

$2 \ mol$ of $N_2O_{4(g)}$ is kept in a closed container at $298 \ K$ and under $1 \ atm$ pressure. It is heated to $596 \ K$ when $20 \%$ by mass of $N_2O_{4(g)}$ decomposes to $NO_2$. The resulting pressure is (in $atm$)

Which of the following equations is incorrect?

$\Delta _f G^o$ at $500 \, K$ for substance '$S$' in liquid state and gaseous state are $+100.7 \, kcal \, mol^{-1}$ and $+103 \, kcal \, mol^{-1}$,respectively. The vapour pressure of liquid '$S$' at $500 \, K$ is approximately equal to $(R = 2 \, cal \, K^{-1} \, mol^{-1}) \dots \dots \text{atm}$.

For the reaction,$0.5 C_{(s)} + 0.5 CO_{2(g)} \rightleftharpoons CO_{(g)}$,the equilibrium pressure is $12 \ atm$. If $CO_2$ conversion is $50 \%$,the value of $K_p$,in $atm$,is:

For the reaction $P_{(g)} + 3Q_{(g)} \rightleftharpoons 4R_{(g)}$,the initial concentrations of $P$ and $Q$ are equal. If the equilibrium concentrations of $P$ and $R$ are equal,then the equilibrium constant $K_c$ for the reaction will be .....