E xleftarrow{KOH/Br_2} D xleftarrow{H_2O_2/OH | vedclass

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(B) $1$. Reaction of $C_2H_5-Cl$ with $NaCN$ gives $C_2H_5CN$ $(C)$.$2$. Partial hydrolysis of $C_2H_5CN$ with $H_2O_2/OH^-$ gives $C_2H_5CONH_2$ $(D)

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Homologue

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(B) $1$. Reaction of $C_2H_5-Cl$ with $NaCN$ gives $C_2H_5CN$ $(C)$.$2$. Partial hydrolysis of $C_2H_5CN$ with $H_2O_2/OH^-$ gives $C_2H_5CONH_2$ $(D)$.$3$. Hofmann bromamide degradation of $C_2H_5CONH_2$ $(D)$ with $KOH/Br_2$ gives $C_2H_5NH_2$ $(E)$.$4$. Reaction of $C_2H_5-Cl$ with $AgCN$ gives $C_2H_5NC$ $(A)$.$5$. Reduction of $C_2H_5NC$ $(A)$ with $LiAlH_4$ gives $C_2H_5NHCH_3$ $(B)$.$6$. $E$ is $C_2H_5NH_2$ (primary amine) and $B$ is $C_2H_5NHCH_3$ (secondary amine).$7$. Both $E$ $(C_2H_7N)$ and $B$ $(C_3H_9N)$ are amines,but they differ by a $-CH_2-$ group,making them homologues.

List-$I$	List-$II$
$a$. Gabriel synthesis	$i$. Benzaldehyde
$b$. Kolbe synthesis	$ii$. Ethers
$c$. Williamson synthesis	$iii$. Primary amines
$d$. Etard reaction	$iv$. Salicylic acid

List-$I$ (Mixture of Compounds)	List-$II$ (Reagent used to distinguish)
$A$. Diethyl amine + Ethyl amine	$I$. Bromine water
$B$. Acetaldehyde + Acetone	$II$. $CHCl_3 + KOH, \Delta$
$C$. Ethanol + Phenol	$III$. Neutral $FeCl_3$
$D$. Benzoic acid + Cinnamic acid	$IV$. Ammonical silver nitrate

$E \xleftarrow{KOH/Br_2} D \xleftarrow{H_2O_2/OH^{-} \atop (Partial \ Hydrolysis)} C \xleftarrow{NaCN} C_2H_5-Cl$ $\xrightarrow{AgCN} A$ $\xrightarrow{LiAlH_4} B$
What is the relationship between $B$ and $E$?

Similar Questions

How many isomeric forms of $C_7H_9N$ contain a benzene ring?

In the given reaction,identify the final product.

Match List-$I$ with List-$II$ :

List-$I$ List-$II$

$a$. Gabriel synthesis $i$. Benzaldehyde

$b$. Kolbe synthesis $ii$. Ethers

$c$. Williamson synthesis $iii$. Primary amines

$d$. Etard reaction $iv$. Salicylic acid

Choose the correct answer from the options given below :

Which of the following reactions does $NOT$ yield an amine?

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$E \xleftarrow{KOH/Br_2} D \xleftarrow{H_2O_2/OH^{-} \atop (Partial \ Hydrolysis)} C \xleftarrow{NaCN} C_2H_5-Cl$ $\xrightarrow{AgCN} A$ $\xrightarrow{LiAlH_4} B$What is the relationship between $B$ and $E$?