$Zn + 2H^+ \to Zn^{2+} + H_2$
The half-life period is independent of the concentration of zinc at constant $pH$. For the constant concentration of $Zn$, the rate becomes $100$ times when $pH$ is decreased from $3\, to\, 2$. Identify the correct statements $(pH = -\log [H^{+}])$
$(A)$ $\frac{{dx}}{{dt}}\, = k{[Zn]^0}{[{H^ + }]^2}$
$(B)$ $\frac{{dx}}{{dt}}\, = k{[Zn]}{[{H^ + }]^2}$
$(C)$ Rate is not affected if the concentraton of zinc is made four times and that of $H^+$ ion is halved.
$(D)$ Rate becomes four times if the concentration of $H^+$ ion is doubled at constant $Zn$ concentration
$A,C$
$A,C$ and $D$
$B,C$ and $D$
None
The order of a reaction with rate equals $kC_A^{3/2}\,C_B^{ - 1/2}$ is
Write differential rate expression of following reaction and give its order of reaction :
$5 B r^{-}+B r O_{3}^-+6 H^{+} \rightarrow 3 B r_{2}+3 H_{2} O$
For the reaction
$2 \mathrm{H}_{2}(\mathrm{g})+2 \mathrm{NO}(\mathrm{g}) \rightarrow \mathrm{N}_{2}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$
the observed rate expression is, rate $=\mathrm{k}_{\mathrm{f}}[\mathrm{NO}]^{2}\left[\mathrm{H}_{2}\right] .$ The rate expression of the reverse reaction is
The reaction, $X + 2Y + Z \to N$ occurs by the following mechanism
$(i)$ $X + Y \rightleftharpoons M$ very rapid equilibrium
$(ii)$ $M + Z \to P$ slow
$(iii)$ $O + Y \to N$ very fast
What is the rate law for this reaction
The experimental data for reaction
$2A + B_2 \longrightarrow 2AB$
Exp. | $[A]$ | $[B_2]$ | Rate $(mol\,L^{-1}\,S^{-1})$ |
$1$ | $0.50$ | $0.50$ | $1.6 \times {10^{ - 4}}$ |
$2$ | $0.50$ | $1.00$ | $3.2 \times {10^{ - 4}}$ |
$3$ | $1.00$ | $1.00$ | $3.2 \times {10^{ - 4}}$ |
The rate law