Which one of the following statements is not correct?

  • A
    Alcohols are weaker acids than water.
  • B
    Acid strength of alcohols decreases in the following order: $RCH_2OH > R_2CHOH > R_3COH$.
  • C
    Carbon-oxygen bond length in methanol, $CH_3OH$ is shorter than that of $C-O$ bond length in phenol.
  • D
    The bond angle $C-O-H$ in methanol is $108.9^o$.

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Explain why the alkoxy $(-OR)$ group is an ortho-para directing and ring-activating group for electrophilic aromatic substitution reactions.

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Benzene $(C_6H_6) + CH_3-CH=CH_2$ $\xrightarrow{H^{\oplus}} A$ $\xrightarrow{O_2} B$ $\xrightarrow{H^{\oplus} / \Delta} C + CH_3-CO-CH_3$
The structure of intermediate compound $B$ will be

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$(I)$ Phenol
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$(IV)$ $p$-Nitrophenol

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