Which one of the following reactions does not take place?

Which of the following reactions is not a redox reaction?

$x, y$ and $z$ are respectively:
$MnO_4^- + x e^- \xrightarrow{\text{Alkaline medium}} MnO_4^{2-}$
$MnO_4^- + y e^- \xrightarrow{\text{Acidic medium}} Mn^{2+}$
$MnO_4^- + z e^- \xrightarrow{\text{Neutral medium}} MnO_2$

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$MnS(s) + 2HCl(aq) \longrightarrow MnCl_2(aq) + H_2S(g)$

To measure the quantity of $MnCl_2$ dissolved in an aqueous solution,it was completely converted to $KMnO_4$ using the reaction,
$MnCl_2 + K_2S_2O_8 + H_2O \longrightarrow KMnO_4 + H_2SO_4 + HCl$ (equation not balanced).
Few drops of concentrated $HCl$ were added to this solution and gently warmed. Further,oxalic acid $(225 \ mg)$ was added in portions till the colour of the permanganate ion disappeared. The quantity of $MnCl_2$ (in $mg$) present in the initial solution is . . . . . . . . . (Atomic weights in $g \ mol^{-1}: Mn = 55, Cl = 35.5$ )

$1 \text{ mole of } H_2C_2O_4 \text{ is oxidised by } x \text{ mole of } MnO_4^- \text{ in strong basic medium and } 1 \text{ mole of } NaHC_2O_4 \text{ is oxidised by } y \text{ mole of } MnO_4^- \text{ in acidic medium. Ratio of } x/y \text{ is}$