Which one of the following pairs of solutions is not an acidic buffer?

$2 \ g$ acetic acid and $3 \ g$ sodium acetate are present in $100 \ mL$ aqueous solution. What will be the $pH$ of the solution if the ionisation constant of acetic acid is $1.8 \times 10^{-5}$?

$50 \ mL$ of $0.02 \ M$ $NaOH$ solution is mixed with $50 \ mL$ of $0.06 \ M$ acetic acid solution. The $pH$ of the resulting solution is $......$ ($pK_a$ of acetic acid is $4.76$,$\log 2 = 0.30$).

The $pK_b$ of $CN^{\Theta}$ is $4.7$. The $pH$ of a solution prepared by mixing $2.5 \ mol$ of $KCN$ and $2.5 \ mol$ of $HCN$ in water and making the total volume up to $500 \ mL$ is:

The $pH$ of blood is maintained due to the mechanism of ...... .

$A$ buffer solution is formed by a weak acid and its salt with a strong base,or a weak base and its salt with a strong acid. In which of the following pairs is this characteristic found?