Which one of the following methods can be used to find out the percentage composition of halogen present in an organic compound?

  • A
    Kjeldahl method
  • B
    Durna's method
  • C
    Lassaigne's method
  • D
    Carius method

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Fill in the blanks:
$(1)$ .......... gas is produced in Kjeldahl's method and absorbed in ...........
$(2)$ The excess $H_2SO_4$ is added in Kjeldahl's method and then the remaining $H_2SO_4$ is titrated with a calculated ..........

In $Duma's$ method of estimation of nitrogen,$0.35 \ g$ of an organic compound gave $55 \ mL$ of nitrogen collected at $300 \ K$ temperature and $715 \ mm$ pressure. The percentage of nitrogen in the compound is (aqueous tension at $300 \ K = 15 \ mm$). (in $.45$)

In the sulphur estimation,$0.471 \, g$ of an organic compound gave $1.44 \, g$ of barium sulphate. The percentage of sulphur in the compound is $...... \%$. (Nearest integer)
(Atomic Mass of $Ba=137 \, u$)

Quantitative measurement of nitrogen in an organic compound is done by the method:

In sulphur estimation,$2.0 \times 10^{-3}$ mol of an organic compound $(X)$ (molar mass $76 \text{ g mol}^{-1}$) gave $0.4813 \text{ g}$ of barium sulphate (molar mass $233 \text{ g mol}^{-1}$). The percentage of sulphur in the compound $(X)$ is . . . . . . $\% \times 10^{-1}$ (Nearest integer).

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