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Why is the adsorption of a gas on a solid exothermic?

Which of the following statements is correct for the Langmuir adsorption isotherm?

Which of the following gas molecules has the maximum value of enthalpy of physisorption?

During adsorption,the $\Delta H$ is negative and the magnitude of this negative value

The Freundlich adsorption isotherm gives a straight line on plotting:

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