Which of the following will increase the voltage of the cell represented by the equation
$Cu_{(s)} + 2Ag^{+}_{(aq)} \to Cu^{2+}_{(aq)} + 2Ag_{(s)}$

  • A
    Increase in the concentration of $Ag^{+}$ ion
  • B
    Increase in the concentration of $Cu^{2+}$ ion
  • C
    Increase in the dimension of $Ag$ electrode
  • D
    Increase in the dimension of $Cu$ electrode

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Consider the cell at $25^{\circ} C$:
$Zn | Zn^{2+}_{(aq)} (1 \ M) || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
The fraction of total iron present as $Fe^{3+}$ ion at the cell potential of $1.500 \ V$ is $X \times 10^{-2}$. The value of $X$ is $.....$ (Nearest integer).
(Given $E^{0}_{Fe^{3+} / Fe^{2+}} = 0.77 \ V, E^{0}_{Zn^{2+} / Zn} = -0.76 \ V$)

$Pt_{(s)} | H_{2(g)}(1 \ bar) | H^{+}_{(aq)}(1 \ M) || M^{3+}_{(aq)}, M^{+}_{(aq)} | Pt_{(s)}$
The $E_{cell}$ for the given cell is $0.1115 \ V$ at $298 \ K$ when $\frac{[M^{+}_{(aq)}]}{[M^{3+}_{(aq)}]} = 10^{a}$.
The value of $a$ is.
Given : $E^{\circ}_{M^{3+}/M^{+}} = 0.2 \ V$
$\frac{2.303 \ RT}{F} = 0.059 \ V$

Give the formula to calculate the equilibrium constant $K_C$ of any electrochemical cell.

Given $E^o _{Cr^{3+} / Cr} = -0.72 \, V$ and $E^o _{Fe^{2+} / Fe} = -0.42 \, V$. The potential for the cell $Cr \, | \, Cr^{3+}_{(0.1 \, M)} \, || \, Fe^{2+}_{(0.01 \, M)} \, | \, Fe$ is ......... $V$.

The equilibrium constant for the following general reaction is $10^{30}$. Calculate $E^{o}$ for the cell at $298 \ K$ ............ $V$
$2X_{2(s)} + 3Y^{2+}_{(aq)} \to 2{X_{2}}^{3+}_{(aq)} + 3Y_{(s)}$

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