Which of the following sulphides is yellow in colour?

Find the compound $A$ from the following reaction sequences:
$A$ $\xrightarrow{\text{aqua-regia}} B$ $\xrightarrow[(2) CH_3COOH]{(1) KNO_2 \mid NH_4OH} \text{yellow ppt}$

On saturating an aqueous solution of $Cu(II)$,$Pb(II)$,and $Zn(II)$ ions with $H_2S$,which of the following will precipitate?

Reagents used for the qualitative estimation of $Ni^{+2}$ and $Cu^{+2}$ respectively are:

Identify the correct reactions and observations from the following:
$(1) \ NH_4^+ \xrightarrow[K_2HgI_4]{KOH} \text{ Brown ppt. (Nessler's reagent)}$
$(2) \ Ni^{2+} \xrightarrow{dmg/OH^-} \text{ Rosy red ppt.}$
$(3) \ FeCl_3(aq.) \xrightarrow{NH_4OH} \text{ Reddish brown ppt.}$
$(4) \ CuSO_4(aq.) \xrightarrow{\text{excess } NH_4OH} \text{ Deep blue solution}$

In the analysis of basic radicals,the group reagent $H_2S$ gas is generally used in which groups?