Which of the following statements is incorrec | vedclass

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(A) According to Werner's theory,negative ligands present in the coordination sphere can satisfy both primary and secondary valencies. In ${K_3}[Fe(CN

Vedclass · Accepted Answer

In ${K_3}[Fe(CN)_6]$,the ligand has satisfied only the secondary valency of ferric ion.

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(A) According to Werner's theory,negative ligands present in the coordination sphere can satisfy both primary and secondary valencies. In ${K_3}[Fe(CN)_6]$,the $CN^-$ ligands satisfy both the primary valency (oxidation state of $Fe$ is $+3$) and the secondary valency (coordination number is $6$). Therefore,statement $(a)$ is incorrect because the ligands satisfy both valencies. Statement $(c)$ is correct because $NH_3$ is a neutral ligand and only satisfies the secondary valency. Since statement $(a)$ is incorrect,the correct choice is $(d)$.

Which of the following statements is incorrect?

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