Which of the following statements is correct?

The molar heat capacity in a process of a diatomic gas,if it does a work of $\frac{Q}{4}$ when a heat of $Q$ is supplied to it,is:

In the arrangement shown in the figure,the masses of blocks $B$ and $A$ are $2m$ and $m$ respectively. The surface between $B$ and the floor is smooth. Block $B$ is connected to block $C$ by means of a string-pulley system. If the whole system is released,find the minimum value of the mass of block $C$ so that block $A$ remains stationary with respect to $B$. The coefficient of friction between $A$ and $B$ is $\mu$.

For the reaction $SnO_{2(s)} + 2H_{2(g)} \rightleftharpoons 2H_2O_{(g)} + Sn_{(l)}$,calculate $K_p$ at $900 \ K$ where the equilibrium steam-hydrogen mixture was $45\%$ $H_2$ by volume.

$A$ block of mass $m$ is at rest on another block of the same mass as shown in the figure. The lower block is attached to a spring. What is the maximum amplitude of motion so that both blocks remain in contact?

Among the second period elements,the actual ionization enthalpies are in the order $Li < B < Be < C < O < N < F < Ne$. Explain why:
$(i)$ $Be$ has higher $\Delta_{i}H$ than $B$.
$(ii)$ $O$ has lower $\Delta_{i}H$ than $N$ and $F$.