Which of the following statements are true about $[CoF_6]^{3-}$ ion?
$I$. The complex has octahedral geometry.
$II$. Coordination number of $Co$ is $3$ and oxidation state is $+6$.
$III$. The complex is $sp^3d^2$ hybridised.
$IV$. It is a high spin complex.

  • A
    $I$,$II$ and $IV$
  • B
    $I$,$III$ and $IV$
  • C
    $II$ and $IV$
  • D
    $II$,$III$ and $IV$

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The incorrect statement about $Ni(CO)_4$ is

In the complex $[SbF_5]^{2-}$,$sp^3d$ hybridisation is present. The geometry of the complex is:

Addition of excess aqueous ammonia to a pink coloured aqueous solution of $MCl_2 \cdot 6H_2O (X)$ and $NH_4Cl$ gives an octahedral complex $Y$ in the presence of air. In aqueous solution,complex $Y$ behaves as a $1:3$ electrolyte. The reaction of $X$ with excess $HCl$ at room temperature results in the formation of a blue coloured complex $Z$. The calculated spin-only magnetic moment of $X$ and $Z$ is $3.87 \ B.M.$,whereas it is zero for complex $Y$.
Among the following options,which statement$(s)$ is(are) correct?
$[A]$ The hybridization of the central metal ion in $Y$ is $d^2sp^3$
$[B]$ $Z$ is a tetrahedral complex
$[C]$ Addition of silver nitrate to $Y$ gives only two equivalents of silver chloride
$[D]$ When $X$ and $Z$ are in equilibrium at $0^{\circ}C$,the colour of the solution is pink

The geometry possessed by $[Ni(CO)_4]$ is

The hybridisation of $Ni$ centre in $[Ni(PPh_3)_2Cl_2]$ and $[NiCl_4]^{2-}$,respectively are

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