Which of the following reactions is $NOT$ correctly represented?

  • A
    $3-$methylcyclohexene + $Br_2, h\nu \rightarrow$ $3-$(bromomethyl)cyclohexene
  • B
    Benzenediazonium chloride + $Cu_2Br_2/HBr \rightarrow$ Bromobenzene
  • C
    Toluene + $Br_2, h\nu \rightarrow$ Benzyl bromide
  • D
    Toluene + $Br_2, Fe, \text{dark} \rightarrow$ Ortho and para bromotoluene

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Rank the following compounds in order of decreasing rate of $E_2$ reaction.

Match the reactions in Column-$I$ with their mechanisms in Column-$II$.
Column-$I$ (Reaction) Column-$II$ (Mechanism)
$(A)$ $OH^- + CH_3Cl \to HOCH_3 + Cl^-$ $(1)$ $S_N2$ mechanism
$(B)$ $(CH_3)_3CBr + OH^- \to (CH_3)_3COH + Br^-$ $(2)$ $S_E2$ aromatic
$(C)$ $CH_3CH_2Br \xrightarrow[ethanol]{KOH} CH_2 = CH_2$ $(3)$ $S_N1$ mechanism
$(D)$ $C_6H_6 + Br_2 \xrightarrow{Fe} C_6H_5Br + HBr$ $(4)$ $\beta$-elimination (dehydrohalogenation)

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Which among the following is $NOT$ obtained when bromobenzene is treated with bromoethane and sodium in the presence of dry ether?

Write the structure of the major organic product in each of the following reactions:
$(i)$ $CH_3-CH_2-CH_2-Cl + NaI \xrightarrow[\text{heat}]{\text{acetone}}$
$(ii)$ $CH_3-C(CH_3)_2-Br + KOH \xrightarrow[\text{heat}]{\text{ethanol}}$
$(iii)$ $CH_3-CH(Br)-CH_2-CH_3 + NaOH \xrightarrow{\text{water}}$
$(iv)$ $CH_3-CH_2-Br + KCN \xrightarrow{\text{aq. ethanol}}$
$(v)$ $C_6H_5-ONa + C_2H_5-Cl \longrightarrow$
$(vi)$ $CH_3-CH_2-CH_2-OH + SOCl_2 \longrightarrow$
$(vii)$ $CH_3-CH_2-CH=CH_2 + HBr \xrightarrow{\text{peroxide}}$
$(viii)$ $CH_3-CH=C(CH_3)_2 + HBr \longrightarrow$

Match the following lists:
List-$I$List-$II$
$(A)$ Benzene$1$. Phosgene
$(B)$ Ethylene$2$. Silver mirror
$(C)$ Acetaldehyde$3$. Mustard gas
$(D)$ Chloroform$4$. $(4n + 2) \pi$ electrons
$5$. Carbylamine

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