Which of the following reactions exhibits good atom economy according to the principles of green chemistry?

  • A
    $C_4H_9OH + NaBr + H_2SO_4 \longrightarrow C_4H_9Br + NaHSO_4 + H_2O$
  • B
    $C_2H_4 + H_2 \xrightarrow{Ni} C_2H_6$
  • C
    $C_2H_5OH + C_2H_5COOH \longrightarrow C_2H_5COOC_2H_5 + H_2O$
  • D
    $C_4H_9OH + SOCl_2 \xrightarrow{\Delta} C_4H_9Cl + HCl + SO_2$

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The molarity of $1 \ L$ orthophosphoric acid $(H_3PO_4)$ having $70 \%$ purity by weight (specific gravity $1.54 \ g \ cm^{-3}$) is $ . . . . . . $ $M$.
(Molar mass of $H_3PO_4 = 98 \ g \ mol^{-1}$)

$50 \ mL$ of $0.5 \ M$ oxalic acid is needed to neutralize $25 \ mL$ of sodium hydroxide solution. The amount in grams of $NaOH$ in $50 \ mL$ of the given sodium hydroxide solution is:

$A$ $20 \ mL$ solution of $KMnO_4$ with a concentration of $1 \ N$ reacts with $20 \ mL$ of oxalic acid. The weight of oxalic acid in the $1 \ N$ solution is ......... $g$.

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The weight of pure $NaOH$ required to prepare $250 \ cm^3$ of $0.1 \ N$ solution is ......... $g$. (in $g$)

Match the following List-$I$ and List-$II$ at $STP$:
List-$I$List-$II$
$A. 10 \ g \ CaCO_3 \xrightarrow{\Delta} \text{decomposition}$$1. 0.224 \ L \ CO_2$
$B. 1.06 \ g \ Na_2CO_3 \xrightarrow{\text{Excess } HCl} \text{reaction}$$2. 4.48 \ L \ CO_2$
$C. 2.4 \ g \ C \xrightarrow{\text{Excess } O_2} \text{combustion}$$3. 0.448 \ L \ CO_2$
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