Which of the following pairs has a heat of neutralisation equal to $13.7 \, Kcal$?

Given
$N_{2(g)} + 3H_{2(g)} \longrightarrow 2NH_{3(g)} \quad \Delta_{r}H^{\theta} = -92.4 \, kJ \, mol^{-1}$
What is the standard enthalpy of formation of $NH_{3}$ gas?

Calculate the heat of formation of $HCl$ gas from the following reaction: $H_{2(g)} + Cl_{2(g)} \rightarrow 2 HCl_{(g)} ; \Delta H = -194 \ kJ$

Given the following thermochemical equations:
$(i) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)} ; \Delta H = -68.39 \, kcal$
$(ii) \ K_{(s)} + H_2O_{(l)} + aq \rightarrow KOH_{(aq)} + \frac{1}{2}H_{2(g)} ; \Delta H = -48.0 \, kcal$
$(iii) \ KOH_{(s)} + aq \rightarrow KOH_{(aq)} ; \Delta H = -14.0 \, kcal$
Calculate the heat of formation of $KOH_{(s)}$.

Given: $H_2 + 1/2 O_2 \rightarrow H_2O : \Delta H = -68.4 \ \text{kcal}$,$C + O_2 \rightarrow CO_2 : \Delta H = -94.0 \ \text{kcal}$,and $C_2H_5OH + 3O_2 \rightarrow 2CO_2 + 3H_2O : \Delta H = -327.0 \ \text{kcal}$. Calculate the heat of formation of $C_2H_5OH$ in $\text{kcal}$.

The enthalpies of formation of $CO_{2(g)}$,$H_2O_{(g)}$,and $C_2H_{4(g)}$ are $-393.7$,$-241.8$,and $52.3 \ kJ \ mol^{-1}$ respectively. What will be the enthalpy of combustion of ethylene at $298 \ K$ and $1 \ atm$ pressure in $kJ \ mol^{-1}$?