Which of the following pairs differ in geometry but resemble in magnetic behavior?

  • A
    $[Ni(CO)_4]$ & $[Ni(CN)_4]^{2-}$
  • B
    $[Be(H_2O)_4]^{2+}$ & $[Zn(CN)_4]^{2-}$
  • C
    $[Fe(CN)_6]^{3-}$ & $[FeF_6]^{3-}$
  • D
    $[Fe(CO)_5]$ & $PCl_5$

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Discuss the $[NiCl_4]^{2-}$ complex species based on Valence Bond Theory.

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The spin-only magnetic moment of $[MnBr_4]^{2-}$ is $5.9 \ BM$. Predict the geometry of the complex ion.

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