Which of the following orbitals is impossible?

The quantum numbers of four electrons are given below:
$I. \ n = 4, l = 2, m_l = -2, m_s = -1/2$
$II. \ n = 3, l = 2, m_l = 1, m_s = +1/2$
$III. \ n = 4, l = 1, m_l = 0, m_s = +1/2$
$IV. \ n = 3, l = 1, m_l = 1, m_s = -1/2$
The correct order of their increasing energies will be:

$A$ subshell with $l = 2$ is called?

Electronic configuration of $Cu$ $(Z = 29)$ is

Which of the following does not follow the Aufbau principle?

Match the columns and choose the correct option:

Column-$I$	Column-$II$
$(a)$ $4s$	$(p)$ Circular orbit around nucleus
$(b)$ $4p$	$(q)$ Non-directional orbital
$(c)$ $1s$	$(r)$ Angular momentum $= 2h/\pi$
$(d)$ $3d$	$(s)$ Radial node is zero