Which of the following molecules/ions can exhibit isomerism:
$A$. Tetrahedral $NiCl_2Br_2^{2-}$$B$. Square planar $Pt(NH_3)_2Cl_2$
$C$. Octahedral $Co(NH_3)_3Cl_3$$D$. Square planar $Pd(NH_3)_3Br^{+}$
$E$. Octahedral $Co(en)_3^{3+}$

Here,$en = 1,2-\text{diaminoethane}$.

  • A
    $A, B, C, D$
  • B
    $B, C, E$
  • C
    $B, C, D$
  • D
    $A, B, C, E$

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The $d-$ electron configurations of $Cr^{2+}, Mn^{2+}, Fe^{2+}$ and $Co^{2+}$ are $d^4, d^5, d^6$ and $d^7$ respectively. Which one of the following will exhibit the lowest paramagnetic behaviour? (Atomic no. $Cr = 24, Mn = 25, Fe = 26, Co = 27$).

Complex $X$ of composition $Cr(H_{2}O)_{6}Cl_{n}$ has a spin-only magnetic moment of $3.83 \ BM$. It reacts with $AgNO_{3}$ and shows geometrical isomerism. The $IUPAC$ nomenclature of $X$ is

Give an example of ionization isomerism.

Number of complexes from the following with an even number of unpaired $d$ electrons is . . . . . . . . . .
$[V(H_2O)_6]^{3+}, \quad [Cr(H_2O)_6]^{2+}, \quad [Fe(H_2O)_6]^{3+}, \quad [Ni(H_2O)_6]^{3+}, \quad [Cu(H_2O)_6]^{2+}$
[Given atomic numbers: $V=23, Cr=24, Fe=26, Ni=28, Cu=29$]

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