Which of the following mixtures in water acts as a basic buffer?

Study the following table:

Buffer Solution	Volume (in $mL$) of $0.1 \ M$ Weak acid	Volume (in $mL$) of $0.1 \ M$ sodium salt of weak acid
$I$	$4.0$	$4.0$
$II$	$4.0$	$40.0$
$III$	$40.0$	$4.0$
$IV$	$0.1$	$10.0$

Which of the two sets of buffer solutions have the least $pH$?

The $pK_a$ of a weak acid is $4.8$. What should be the ratio of $\frac{[\text{acid}]}{[\text{salt}]}$,if a buffer of $pH = 5.8$ is required?

$50 \, mL$ of $0.2 \, M$ ammonia solution is treated with $25 \, mL$ of $0.2 \, M$ $HCl$. If $pK_b$ of ammonia solution is $4.75$,the $pH$ of the mixture will be

If a small amount of sodium acetate is added to an equimolar mixture of sodium acetate and acetic acid,the $pH$ of the resulting solution will .......

$A$ buffer solution is prepared by mixing equimolar acetic acid and sodium acetate. If $K_{a}$ of acetic acid is $1.78 \times 10^{-5}$,find the $pH$ of the buffer solution.